THE POLYMER SOCIETY OF KOREA

연구논문 초록집

초록 검색

세션명 기능성 고분자(III)
발표장 포스터장
논문코드 3PS-205
발표일 2019-10-11
발표시간 16:00-17:30 (게시시간: 13:50-17:30)
논문제목 Fluorous Ligands and their effect on Long Term Stability of Mixed Halide Perovskites
발표자 김영민
발표자 소속 한남대학교
저자 김영민, PREM PRABHAKARAN
소속 한남대학교
논문초록 Stability is a major deterrent to the mainstream application of mixed halide perovskites. The ionic nature of halide perovskites makes them vulnerable in the atmosphere and in polar solvents. Herein, we report a one-pot synthesis of mixed halide perovskite QDs in the presence of fluorous fatty acids along with oleic acid (OA) and oleylamine (OAm). The introduction of fluorous acid is aimed at improving the environmental stability of QDs. The relative composition of fluorous fatty acids during synthesis influences the size, form and optical properties of QDs. Higher concentrations of fluorous acids lead to 2D perovskites. Temperature-dependent phase segregation between fluorous carboxylic acid and OAm leads to structure and color variation in synthesized nanomaterials.